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The review observes the published literature data concerning preparative reactions for the synthesis of 1-oxa-2-phosphol-3-enium salts and highlights the experimental procedures and their analytical NMR, IR, melting points data. The salts were prepared by the reaction of phosphorus-containing allenes with protic acids, Hal2, and R-Hal. The stability and reactivity of the salts discussed with the support of DFT-calculations. The review covers 64 references. |
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